ISOBUTYLMAGNESIUM BROMIDE
isobutylmagnesium bromide
CAS: 926-62-5
Molecular Formula: C4H9BrMg
ISOBUTYLMAGNESIUM BROMIDE - Names and Identifiers
| Name | isobutylmagnesium bromide |
| Synonyms | isobutylmagnesium bromide ISOBUTYLMAGNESIUM BROMIDE Isobutylmagnesium(1+) bromide 2-Methylpropylmagnesium bromide Isobutylmagnesium bromide solution (2-methylpropyl)magnesium(1+) bromide Isobutylmagnesium Bromide 1.0 M In Tetrahydrofuran Isobutylmagnesium bromide solution 2.0 in diethyl ether ISOBUTYLMAGNESIUM BROMIDE, 2.0M SOLUTION IN DIETHYL ETHER Isobutylmagnesium bromide, 2M solution in diethyl ether, AcroSeal |
| CAS | 926-62-5 |
| InChI | InChI=1/C4H9.BrH.Mg/c1-4(2)3;;/h4H,1H2,2-3H3;1H;/q;;+1/p-1/rC4H9Mg.BrH/c1-4(2)3-5;/h4H,3H2,1-2H3;1H/q+1;/p-1 |
| InChIKey | CMWBEISSZHZIMU-UHFFFAOYSA-M |
ISOBUTYLMAGNESIUM BROMIDE - Physico-chemical Properties
| Molecular Formula | C4H9BrMg |
| Molar Mass | 161.32 |
| Density | 0.941g/mLat 25°C |
| Melting Point | 51-53℃ |
| Boling Point | 122-123℃ (0.2 Torr) |
| Flash Point | <−30°F |
ISOBUTYLMAGNESIUM BROMIDE - Risk and Safety
| Risk Codes | R12 - Extremely Flammable R14/15 - R19 - May form explosive peroxides R22 - Harmful if swallowed R34 - Causes burns R67 - Vapors may cause drowsiness and dizziness R66 - Repeated exposure may cause skin dryness or cracking |
| Safety Description | S16 - Keep away from sources of ignition. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) |
| UN IDs | UN 3399 4.3/PG 1 |
| WGK Germany | 1 |
| HS Code | 29319090 |
| Hazard Class | 4.2 |
| Packing Group | I |
ISOBUTYLMAGNESIUM BROMIDE - Introduction
isobutylmagnesium bromide is an organometallic compound with the chemical formula (CH3)2 CHCH2MgBr. The following is a description of the nature, use, preparation and safety information of isobutylmagnesium bromide:
Nature:
-Appearance is colorless or light yellow liquid.
-Soluble in organic solvents such as ethers and hydrocarbons.
-It has a high degree of humidity sensitivity in the air and is easy to decompose.
Use:
- isobutylmagnesium bromide is an important reagent in organic synthesis and can be used to synthesize various organic compounds, such as alcohols, ethers, ketones, carboxylic acids, etc.
-It can be used as an addition reagent, nucleophile, reducing agent and filler of alkenes and alkynes.
Method:
The preparation of isobutylmagnesium bromide is usually carried out by the following steps:
1. Dissolve isobutyl lithium in anhydrous ether.
2. slowly drop magnesium bromide at low temperature.
3. After completion of the reaction, a isobutylmagnesium bromide solution was obtained.
Safety Information:
- isobutylmagnesium bromide are highly moisture sensitive and should be stored and handled under the protection of inert gas.
-Because it is an organometallic compound, it is dangerous and volatile for non-professionals, so you need to be careful and take appropriate safety measures when using it.
-When using isobutylmagnesium bromide for chemical reactions, it should be done in a well-ventilated place and wear appropriate personal protective equipment.
-Follow laboratory safety practices and correct waste disposal in accordance with relevant regulations.
Nature:
-Appearance is colorless or light yellow liquid.
-Soluble in organic solvents such as ethers and hydrocarbons.
-It has a high degree of humidity sensitivity in the air and is easy to decompose.
Use:
- isobutylmagnesium bromide is an important reagent in organic synthesis and can be used to synthesize various organic compounds, such as alcohols, ethers, ketones, carboxylic acids, etc.
-It can be used as an addition reagent, nucleophile, reducing agent and filler of alkenes and alkynes.
Method:
The preparation of isobutylmagnesium bromide is usually carried out by the following steps:
1. Dissolve isobutyl lithium in anhydrous ether.
2. slowly drop magnesium bromide at low temperature.
3. After completion of the reaction, a isobutylmagnesium bromide solution was obtained.
Safety Information:
- isobutylmagnesium bromide are highly moisture sensitive and should be stored and handled under the protection of inert gas.
-Because it is an organometallic compound, it is dangerous and volatile for non-professionals, so you need to be careful and take appropriate safety measures when using it.
-When using isobutylmagnesium bromide for chemical reactions, it should be done in a well-ventilated place and wear appropriate personal protective equipment.
-Follow laboratory safety practices and correct waste disposal in accordance with relevant regulations.
Last Update：2024-04-10 22:29:15
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